Removal of Antibiotic-Metal Complexes in Wastewater by Electrochemical Methods: A Review

Vista sencilla de ítem
dc.creatorSánchez-Medina, Andrés F.
dc.creatorRomero-Sáez, Manuel
dc.creatorRamírez-Sánchez, Carolina
dc.date2025-05-31
dc.date.accessioned2025-10-01T23:53:16Z
dc.descriptionThe presence of antibiotics and metals in wastewater leads to alteration of antibiotic resistance genes (ARGs). Concentrations of both species have been detected in municipal wastewater in the range of tens of µg/L, promoting the formation of antibiotic–metal complexes. These complexes are more stable and hazardous to the ecosystem than their individual components. The objective of this review was to analyze antibiotic-metal complexes present in wastewater, their physicochemical properties, and toxicological effects, as well as to evaluate the electrochemical techniques used for their removal or recovery, and their integration with other treatment methods. A comprehensive literature review was conducted using major scientific databases such as Science Direct, Scopus, ACS Publications, PubMed, and Web of Science, selecting the 111 most representative studies. The results showed that electrochemical methods represent a promising tool for the efficient treatment of water contaminated with these complexes, as they offer the advantages of both antibiotic degradation and metal recovery, benefits not achieved by conventional treatments. Among the treatments reviewed, photoelectrocatalysis emerged as the most efficient method, showing high rates of antibiotic degradation within short treatment times. This efficiency is attributed to the synergy between light activation of a semiconductor anode and applied electric current, which leads to the generation of strong oxidizing agents.en-US
dc.descriptionLa presencia de antibióticos y metales en aguas residuales provoca la modificación de genes con resistencia bacteriana (ARG). Se han encontrado concentraciones de ambas especies en decenas de µg/L en aguas residuales municipales, lo que promueve la formación de complejos antibiótico-metal, generando así compuestos más estables y peligrosos para el ecosistema que sus entes individuales. El objetivo de esta revisión fue analizar los complejos antibiótico-metal presentes en aguas residuales, sus propiedades fisicoquímicas y efectos toxicológicos, así como evaluar las técnicas electroquímicas utilizadas para su eliminación o recuperación y su integración con otros tratamientos. Para ello se realizó una revisión de la literatura existente en la temática en las principales bases de datos científicas, como Science Direct, Scopus, ACS Publications, PubMed y Web of Science, seleccionado los 111 trabajos más representativos. Los resultados mostraron que los métodos electroquímicos se presentan como una herramienta prometedora para el tratamiento eficiente de aguas contaminadas con estos complejos, ya que tienen la ventaja de lograr la degradación del antibiótico y la recuperación del metal, lo que no logran otros tratamientos convencionales. De los tratamientos revisados, se puede concluir que el método fotoelectrocatalítico resulta ser el más eficiente por mostrar altos porcentajes de degradación de los antibióticos en cortos tiempos de tratamiento. Esto se debe a la sinergia entre la acción de la luz en un ánodo semiconductor y la corriente eléctrica aplicada que provoca la generación de oxidantes fuertes.es-ES
dc.formatapplication/pdf
dc.formattext/xml
dc.formatapplication/zip
dc.identifierhttps://revistas.itm.edu.co/index.php/tecnologicas/article/view/3344
dc.identifier10.22430/22565337.3344
dc.identifier.urihttps://hdl.handle.net/20.500.12622/7939
dc.languagespa
dc.publisherInstituto Tecnológico Metropolitano (ITM)es-ES
dc.relationhttps://revistas.itm.edu.co/index.php/tecnologicas/article/view/3344/3672
dc.relationhttps://revistas.itm.edu.co/index.php/tecnologicas/article/view/3344/3678
dc.relationhttps://revistas.itm.edu.co/index.php/tecnologicas/article/view/3344/3788
dc.relationhttps://revistas.itm.edu.co/index.php/tecnologicas/article/view/3344/3789
dc.relation/*ref*/A. Kotwani, J. Joshi, and D. Kaloni, “Pharmaceutical effluent: a critical link in the interconnected ecosystem promoting antimicrobial resistance,” Environ. Sci. Pollut. Res., vol. 28, pp. 32111–32124, Jul. 2021. https://doi.org/10.1007/s11356-021-14178-w
dc.relation/*ref*/A. J. Watkinson, E. J. Murby, D. W. Kolpin, and S. D. Costanzo, “The occurrence of antibiotics in an urban watershed: From wastewater to drinking water,” Sci. Total Environ., vol. 407, no. 8, pp. 2711–2723, Apr. 2009. https://doi.org/10.1016/j.scitotenv.2008.11.059
dc.relation/*ref*/S. Yuan, X. Jiang, X. Xia, H. Zhang, and S. Zheng, “Detection, occurrence and fate of 22 psychiatric pharmaceuticals in psychiatric hospital and municipal wastewater treatment plants in Beijing, China,” Chemosphere, vol. 90, no. 10, pp. 2520–2525, Mar. 2013. https://doi.org/10.1016/j.chemosphere.2012.10.089
dc.relation/*ref*/J. Kwon Im, M. Young Hwang, E. Hee Lee, H. Ran Noh, and S. Ju Yu, “Pharmaceutical compounds in tributaries of the Han River watershed, South Korea,” Environ. Res., vol. 188, p. 109758. Sep. 2020. https://doi.org/10.1016/j.envres.2020.109758
dc.relation/*ref*/D. Ramírez-Morales et al., “Pharmaceuticals, hazard and ecotoxicity in surface and wastewater in a tropical dairy production area in Latin America,” Chemosphere, vol. 346, p. 140443. Jan. 2024. https://doi.org/10.1016/j.chemosphere.2023.140443
dc.relation/*ref*/A. M. Botero-Coy et al., “An investigation into the occurrence and removal of pharmaceuticals in Colombian wastewater,” Sci. Total Environ., vol. 642, pp. 842–853, Nov. 2018. https://doi.org/10.1016/j.scitotenv.2018.06.088
dc.relation/*ref*/S. Khan, I. Ahmad, M. Tahir Shah, S. Rehman, and A. Khaliq, “Use of constructed wetland for the removal of heavy metals from industrial wastewater,” J. Environ. Manage, vol. 90, no. 11, pp. 3451–3457, Aug. 2009. https://doi.org/10.1016/j.jenvman.2009.05.026
dc.relation/*ref*/C. Doria-Argumedo, “Metales pesados (Cd, Cu, V, Pb) en agua lluvia de la zona de mayor influencia de la mina de carbón en La Guajira, Colombia,” Rev. Colomb. Quim., vol. 46, no. 2, pp. 37–44, May. 2017. https://doi.org/10.15446/rev.colomb.quim.v46n2.60533
dc.relation/*ref*/J.-G. Yu et al., “Graphene nanosheets as novel adsorbents in adsorption, preconcentration and removal of gases, organic compounds and metal ions,” Sci. Total Envirom., vol. 502, pp. 70-79, Jan. 2015. https://doi.org/10.1016/j.scitotenv.2014.08.077
dc.relation/*ref*/R.-S. Juang and S.-W. Wang, “Electrolytic recovery of binary metals and EDTA from strong complexed solutions,” Water Res., vol. 34, no. 12, pp. 3179–3185, Aug. 2000. https://doi.org/10.1016/S0043-1354(00)00061-0
dc.relation/*ref*/Q. Yan, Z. Zhong, X. Li, Z. Cao, X. Zheng, and G. Feng, “Characterization of heavy metal, antibiotic pollution, and their resistance genes in paddy with secondary municipal-treated wastewater irrigation,” Water Res., vol. 252, p. 121208, Mar. 2024. https://doi.org/10.1016/j.watres.2024.121208
dc.relation/*ref*/I. Ijaz et al., “Simultaneous adsorption of sulfamethoxazole and neodymium from wastewater by a MXene-, α-aminophosphonate-, and sulfated fucan-based ternary composite based on anion-synergistic interactions,” RSC Adv., vol. 15, no. 7, pp. 5042–5059, Feb. 2025. https://doi.org/10.1039/D4RA08766F
dc.relation/*ref*/Y. Zhu, W. Fan, T. Zhou, and X. Li, “Removal of chelated heavy metals from aqueous solution: A review of current methods and mechanisms,” Sci. Total Environ., vol. 678, pp. 253–266, Aug. 2019. https://doi.org/10.1016/j.scitotenv.2019.04.416
dc.relation/*ref*/E. Elsayed, “The Role of Electrochemistry and Electrochemical Technology in Environmental Protection, a review,” Int. J. Mater. Tech. Innov., vol. 3, no. 2, pp. 37–63, Jun. 2023. https://ijmti.journals.ekb.eg/article_304724.html
dc.relation/*ref*/W. Guan, B. Zhang, S. Tian, and X. Zhao, “The synergism between electro-Fenton and electrocoagulation process to remove Cu-EDTA,” Appl. Catal. B., vol. 227, pp. 252–257, Jul. 2018. https://doi.org/10.1016/j.apcatb.2017.12.036
dc.relation/*ref*/J. A. Byrne, B. R. Eggins, W. Byers, and N. M. D. Brown, “Photoelectrochemical cell for the combined photocatalytic oxidation of organic pollutants and the recovery of metals from waste waters,” Appl. Catal. B., vol. 20, no. 2. pp. L85-L89, Feb. 1999. https://doi.org/10.1016/S0926-3373(98)00103-9
dc.relation/*ref*/J. L. Wilkinson et al., “Pharmaceutical pollution of the world’s rivers,” Proc. Natl. Acad. Sci. U.S.A., vol. 119, no. 8, p. e2113947119, Feb. 2022. https://doi.org/10.1073/pnas.2113947119
dc.relation/*ref*/M. Li, X. Xi, Z. Nie, L. Ma, and Q. Liu, “Recovery of tungsten from WC-Co hard metal scraps using molten salts electrolysis,” J. Mater. Res. Techn., vol. 8, no. 1, pp. 1440–1450, Jan-Mar. 2019. https://doi.org/10.1016/j.jmrt.2018.10.010
dc.relation/*ref*/O. V. Nkwachukwu, C. Muzenda, B. A. Koiki, and O. A. Arotiba, “Perovskites in photoelectrocatalytic water treatment: Bismuth ferrite - graphite nanoparticles composite photoanode for the removal of ciprofloxacin in water,” J. Photochem. Photobiol. A Chem., vol. 434, p. 114275. Jan. 2023. https://doi.org/10.1016/j.jphotochem.2022.114275
dc.relation/*ref*/A. Mattheew Wilson, P. J. Bailey, P. A. Tasker, J. R. Turkington, R. A. Grant, and J. B. Love, “Solvent extraction: The coordination chemistry behind extractive metallurgy,” Chem. Soc. Rev., vol. 43, no. 1, pp. 123-134, Oct. 2013. https://doi.org/10.1039/C3CS60275C
dc.relation/*ref*/D. Kołodyńska, “Complexing Agents,” in Kirk-Othmer Encyclopedia of Chemical Technology. Hoboken, New Jersey, USA: Wiley, 2019, pp. 1–26. https://doi.org/10.1002/0471238961.0308051208152301.a01.pub3
dc.relation/*ref*/A. A. Azmi, J. Jai, N. A. Zamanhuri, and A. Yahya, “Precious Metals Recovery from Electroplating Wastewater: A Review,” in IOP Conf. Ser.: Mater. Sci. Eng., vol. 358, 3rd Int. Conf. Glob. Sustain. Chem. Eng. (ICGSCE), Bristol, Eng: Institute of Physics Publishing, 2018, p. 012024. https://iopscience.iop.org/article/10.1088/1757-899X/358/1/012024
dc.relation/*ref*/F. C. Coelho et al., “Agricultural use of copper and its link to Alzheimer’s disease,” Biomolecules, vol. 10, no. 6, p. 897, Jun. 2020. https://doi.org/10.3390/biom10060897
dc.relation/*ref*/E. Kyung Choe, Y.-Z. Kim, Y. Dal Cho, and S. Hwan Son, “Study on analytical scheme for human ecological quality control of chromium-complex acid dyes,” Text. Res. J., vol. 86, no. 17, pp. 1847–1858, Nov. 2015. https://doi.org/10.1177/0040517515617421
dc.relation/*ref*/P. Bača, and P. Vanýsek, “Issues Concerning Manufacture and Recycling of Lead,” Energies (Basel), vol. 16, no. 11, p. 4468, Jun. 2023. https://doi.org/10.3390/en16114468
dc.relation/*ref*/P. Khurana, R. Pulicharla, and S. Kaur Brar, “Antibiotic-metal complexes in wastewaters: fate and treatment trajectory,” Environ. Int., vol. 157, p. 106863, Dec. 2021. https://doi.org/10.1016/j.envint.2021.106863
dc.relation/*ref*/S. Sharan, P. Khare, and R. Shankar, “Electrochemical degradation of ofloxacin using PbO2/Pb-based lead acid battery electrode: Parametric optimization and kinetics study,” Mater. Today Proc., vol. 78, part 1, pp. 128–137, 2023. https://doi.org/10.1016/j.matpr.2022.12.195
dc.relation/*ref*/P. Khurana, R. Pulicharla, and S. Kaur Brar, “Analytical challenges of antibiotic-metal complexes in wastewaters: A mini-review,” Environ. Nanotechnol. Monit. Manag., vol. 18, p. 100747, Dec. 2022. https://doi.org/10.1016/j.enmm.2022.100747
dc.relation/*ref*/J. Lu, J. Wu, C. Zhang, Y. Zhang, Y. Lin, and Y. Luo, “Occurrence, distribution, and ecological-health risks of selected antibiotics in coastal waters along the coastline of China,” Sci. Total Environ., vol. 644, pp. 1469–1476, Dec. 2018. https://doi.org/10.1016/j.scitotenv.2018.07.096
dc.relation/*ref*/X. Liu, S. Lu, W. Guo, B. Xi, and W. Wang, “Antibiotics in the aquatic environments: A review of lakes, China,” Sci. Total Environ., vol. 627, pp. 1195-1208, Jun. 2018. https://doi.org/10.1016/j.scitotenv.2018.01.271
dc.relation/*ref*/R. E. Fernández Rodríguez, H. Bolívar Anillo, C. Hoyos Turcios, L. Carrillo García, M. Serrano Hernández, and E. Abdellah, “Antibiotic resistance: the role of man, animals and the environment,” Salud Uninorte, vol. 36, no. 1, pp. 298–324, Jan-Apr. 2020. http://dx.doi.org/10.14482/sun.36.1.615
dc.relation/*ref*/K.-J. Appenroth, “Definition of ‘Heavy Metals’ and Their Role in Biological Systems,” in Soil Biology, Berlin, Heidelberg: Springer Berlin Heidelberg, 2010, pp. 19–29. https://doi.org/10.1007/978-3-642-02436-8_2
dc.relation/*ref*/H. Ali, and E. Khan, “Trophic transfer, bioaccumulation, and biomagnification of non-essential hazardous heavy metals and metalloids in food chains/webs—Concepts and implications for wildlife and human health,” Human and Ecogical Risk Assessment: An International Journal, vol. 25, no. 6, pp. 1353–1376, Aug. 2019. https://doi.org/10.1080/10807039.2018.1469398
dc.relation/*ref*/M. Kumar, K. Kaur Sodhi, P. Singh, P. Kumar Agrawal, and D. Kumar Singh, “Synthesis and characterization of antibiotic-metal complexes [FeCl3(L1)2H2O and Ni(NO3)2(L2)2H2O] and enhanced antibacterial activity,” Environ. Nanotechnol. Monit. Manag., vol. 11, p. 100209, May 2019. https://doi.org/10.1016/j.enmm.2019.100209
dc.relation/*ref*/G. Psomas, and D. P. Kessissoglou, “Quinolones and non-steroidal anti-inflammatory drugs interacting with copper(ii), nickel(ii), cobalt(ii) and zinc(ii): Structural features, biological evaluation and perspectives,” Dalton Trans., vol. 42, no. 18, pp. 6252-6276, Feb. 2013. https://doi.org/10.1039/C3DT50268F
dc.relation/*ref*/R. Puicharla, D. P. Mohapatra, S. K. Brar, P. Drogui, S. Auger, and R. Y. Surampalli, “A persistent antibiotic partitioning and co-relation with metals in wastewater treatment plant - Chlortetracycline,” J. Environ. Chem. Eng., vol. 2, no. 3, pp. 1596–1603, Sep. 2014. https://doi.org/10.1016/j.jece.2014.06.001
dc.relation/*ref*/Q. Wang, X. He, H. Xiong, Y. Chen, and L. Huang, “Structure, mechanism, and toxicity in antibiotics metal complexation: Recent advances and perspectives,” Sci. Total. Environ., vol. 848, p. 157778, Nov. 2022. https://doi.org/10.1016/j.scitotenv.2022.157778
dc.relation/*ref*/P. Lu, Y. Wu, H. Kang, H. Wei, H. Liu, and M. Fang, “What can pKaand NBO charges of the ligands tell us about the water and thermal stability of metal organic frameworks?,” J. Mater. Chem. A, vol. 2, no. 38, pp. 16250–16267, Aug. 2014. https://doi.org/10.1039/C4TA03154G
dc.relation/*ref*/B. P. Hay, A. Chagnes, and G. Cote, “On the Metal Ion Selectivity of Oxoacid Extractants,” Solvent Extr. Ion Exch., vol. 31, no. 1, pp. 95–105, Dec. 2012. https://doi.org/10.1080/07366299.2012.709452
dc.relation/*ref*/Z. Qiang, and C. Adams, “Potentiometric determination of acid dissociation constants (pK a) for human and veterinary antibiotics,” Water Res., vol. 38, no. 12, pp. 2874–2890, Jul. 2004. https://doi.org/10.1016/j.watres.2004.03.017
dc.relation/*ref*/R. Li, S. E. Williams, Q. Li, J. Zhang, C. Yang, and A. Zhou, “Photoelectrocatalytic Degradation of Ofloxacin Using Highly Ordered TiO2 Nanotube Arrays,” Electrocatalysis, vol. 5, no. 4, pp. 379–386, Oct. 2014. https://doi.org/10.1007/s12678-014-0204-3
dc.relation/*ref*/J. W. Peterson, L. J. Petrasky, M. D. Seymour, and R. S. Bergmans, “Laboratory Investigation of Antibiotic Interactions with Fe2O3 Nanoparticles in Water,” J. Environ. Engin., vol. 142, no. 5, Jan. 2016. https://doi.org/10.1061/(ASCE)EE.1943-7870.0001090
dc.relation/*ref*/A. Cuprys, R. Pulicharla, S. Kaur Brar, P. Drogui, M. Verma, and R. Y. Surampalli, “Fluoroquinolones metal complexation and its environmental impacts,” Coord. Chem. Rev., vol. 376, pp. 46-61, Dec. 2018. https://doi.org/10.1016/j.ccr.2018.05.019
dc.relation/*ref*/H. R. Park, G. Y. Jeong, H. C. Lee, J. G. Lee, and G. M. Baek, “Ionization and Divalent Cation Complexation of Quinolone Antibiotics in Aqueous Solution,” Bull. Korean Chem. Soc., vol. 21, no. 9, pp. 849-854, Sep. 2000. https://koreascience.kr/article/JAKO200013464477305.page
dc.relation/*ref*/V. Uivarosi, “Metal complexes of quinolone antibiotics and their applications: An update,” Molec., vol. 18, no. 9, pp. 11153-11197, Sep. 2013. https://doi.org/10.3390/molecules180911153
dc.relation/*ref*/I. Turel, N. Bukovec, and E. Farkas, “Complex formation between some metals and a quinolone family member (ciprofloxacin),” Polyhedron, vol. 15, no. 2, pp. 269–275, Jan. 1996. https://doi.org/10.1016/0277-5387(95)00231-G
dc.relation/*ref*/K. Siddappa, S. B. Mane, and D. Manikprabhu, “Spectral characterization and 3D molecular modeling studies of metal complexes involving the O, N-donor environment of quinazoline-4(3H)-one Schiff base and their biological studies,” Sci. World J., p. 817365, Feb. 2014. https://doi.org/10.1155/2014/817365
dc.relation/*ref*/A. T. Abdelkarim, W. H. Mahmoud, and A. A. El-Sherif, “Potentiometric, thermodynamics and coordination properties for binary and mixed ligand complexes of copper (II) with cephradine antibiotic and some N- and O-bound amino acids (α-alanine and β-alanine),” J. Mol. Liq., vol. 328, p. 115334. Apr. 2021. https://doi.org/10.1016/j.molliq.2021.115334
dc.relation/*ref*/H. Kaur, J. K. Puri, and A. Singla, “Metal ion interactions with drugs: Electrochemical study of complexation of various bivalent metal ions with nimesulide and ibuprofen,” J. Mol. Liq., vol. 182, pp. 39–42, Jun. 2013. https://doi.org/10.1016/j.molliq.2013.03.005
dc.relation/*ref*/A. Cuprys, R. Pulicharla, J. Lecka, S. K. Brar, P. Drogui, and R. Y. Surampalli, “Ciprofloxacin-metal complexes –stability and toxicity tests in the presence of humic substances,” Chemosphere, vol. 202, pp. 549–559, Jul. 2018. https://doi.org/10.1016/j.chemosphere.2018.03.117
dc.relation/*ref*/S. Rakshit, D. Sarkar, E. J. Elzinga, P. Punamiya, and R. Datta, “Surface Complexation of Oxytetracycline by Magnetite: Effect of Solution Properties,” Vadose Zone Journal, vol. 13, no. 2, pp. 1–10, Feb. 2014. https://doi.org/10.2136/vzj2013.08.0147
dc.relation/*ref*/L. Zhu, X. Lin, Z. Di, F. Cheng, and J. Xu, “Occurrence, Risks, and Removal Methods of Antibiotics in Urban Wastewater Treatment Systems: A Review,” Water, vol. 16, no. 23, p. 3428, Nov. 2024. https://doi.org/10.3390/w16233428
dc.relation/*ref*/N. Iftikhar et al., “Sulfamethoxazole (SMX) Alters Immune and Apoptotic Endpoints in Developing Zebrafish (Danio rerio),” Toxics, vol. 11, no. 2, p. 178, Feb. 2023. https://doi.org/10.3390/toxics11020178
dc.relation/*ref*/J. Hao, X. Wang, Y. Wang, Y. Wu, and F. Guo, “Optimizing the Leaching Parameters and Studying the Kinetics of Copper Recovery from Waste Printed Circuit Boards,” ACS Omega, vol. 7, no. 4, pp. 3689–3699, Jan. 2022. https://doi.org/10.1021/acsomega.1c06173
dc.relation/*ref*/H. Guo, S. Xue, M. Nasir, J. Gu, and J. Lv, “Impacts of cadmium addition on the alteration of microbial community and transport of antibiotic resistance genes in oxytetracycline contaminated soil,” J. Environ. Sci., vol. 99, pp. 51–58, Jan. 2021. https://doi.org/10.1016/j.jes.2020.04.015
dc.relation/*ref*/A. A. Roberto, J. B. Van Gray, J. Engohang-Ndong, and L. G. Leff, “Distribution and co-occurrence of antibiotic and metal resistance genes in biofilms of an anthropogenically impacted stream,” Sci. Total Environ., vol. 688, pp. 437–449, Oct. 2019. https://doi.org/10.1016/j.scitotenv.2019.06.053
dc.relation/*ref*/J. C. Thomas et al., “Co-occurrence of antibiotic, biocide, and heavy metal resistance genes in bacteria from metal and radionuclide contaminated soils at the Savannah River Site,” Microb. Biotechnol., vol. 13, no. 4, pp. 1179–1200, Jul. 2020. https://doi.org/10.1111/1751-7915.13578
dc.relation/*ref*/J. Hao, X. Wang, Y. Wang, F. Guo, and Y. Wu, “Study of gold leaching from pre-treated waste printed circuit boards by thiosulfate cobalt-glycine system and separation by solvent extraction,” Hydrometallurgy, vol. 221, p. 106141, Aug. 2023. https://doi.org/10.1016/j.hydromet.2023.106141
dc.relation/*ref*/N. Li, J. Chen, C. Liu, J. Yang, C. Zhu, and H. Li, “Cu and Zn exert a greater influence on antibiotic resistance and its transfer than doxycycline in agricultural soils,” J. Hazardous Mater., vol. 423, no. Part. B, p. 127042, Feb. 2022. https://doi.org/10.1016/j.jhazmat.2021.127042
dc.relation/*ref*/X. Wang, B. Lan, H. Fei, S. Wang, and G. Zhu, “Heavy metal could drive co-selection of antibiotic resistance in terrestrial subsurface soils,” J. Hazardous Mater., vol. 411, p. 124848, Jun. 2021. https://doi.org/10.1016/j.jhazmat.2020.124848
dc.relation/*ref*/I. Lozano, C. J. Pérez-Guzmán, A. Mora, J. Mahlknecht, C. López Aguilar, and P. Cervantes-Avilés, “Pharmaceuticals and personal care products in water streams: Occurrence, detection, and removal by electrochemical advanced oxidation processes,” Sci. Total Environ., vol. 821, p. 154348, Jun. 2022. https://doi.org/10.1016/j.scitotenv.2022.154348
dc.relation/*ref*/Ministerio de Ambiente y Desarrollo Sostenible, “Resolución 0631 de 2015,” 17 Mar. 2015. https://www.minambiente.gov.co/wp-content/uploads/2021/11/resolucion-631-de-2015.pdf
dc.relation/*ref*/T. Austiono Kurniawan, G. Y. S. Chan, W.-H. Lo, and S. Babel, “Physico-chemical treatment techniques for wastewater laden with heavy metals,” Chem. Eng. J., vol. 118, no. 1–2, pp. 83–98, May. 2006. https://doi.org/10.1016/j.cej.2006.01.015
dc.relation/*ref*/Y. Zhou et al., “Determining discharge characteristics and limits of heavy metals and metalloids for wastewater treatment plants (WWTPs) in China based on statistical methods,” Water (Switz.), vol. 10, no. 9, p. 1248, Sep. 2018. https://doi.org/10.3390/w10091248
dc.relation/*ref*/P. Kaur, J. Prakash Kushwaha, and V. Kumar Sangal, “Electrocatalytic oxidative treatment of real textile wastewater in continuous reactor: Degradation pathway and disposability study,” J. Hazardous Mater., vol. 346, pp. 242–252, Mar. 2018. https://doi.org/10.1016/j.jhazmat.2017.12.044
dc.relation/*ref*/J. Pinedo-Hernández, Y. Núñez, I. Sánchez, and J. Marrugo-Negrete, “Treatment of meat industry wastewater using electrochemical treatment method,” Port. Electrochim. Acta, vol. 33, no. 4, pp. 223–230, Nov. 2015. https://doi.org/10.4152/pea.201504223
dc.relation/*ref*/N. B. Singh, and A. B. H. Susan, “Polymer nanocomposites for water treatments,” in Polymer-based Nanocomposites for Energy and Environmental Applications: A volume in Woodhead Publishing Series in Composites Science and Engineering, M. Jawaid, and M. Mansoob Khan, Eds., Ottawa, Canadá: University of Ottawa Press-Woodhead Publishing, 2018, pp. 569–595. https://doi.org/10.1016/B978-0-08-102262-7.00021-0
dc.relation/*ref*/A. J. Bard, and L. R. Faulkner, Electrochemical Methods, Fundamentals and Applications, Hoboken, New Jersey, USA: Wiley, 1983. https://pubs.acs.org/doi/abs/10.1021/ed060pA25.1
dc.relation/*ref*/H. M. Zelada Romero, and C. Vásquez, “Evaluation of the Efficiency of an Electrocoagulation Cell for the Treatment of Wastewater coming from the Textile Industry,” in Proc. LACCEI Int. Multi-conference Engin., Educ. Techn., Boca Raton, FL, USA, 2023. https://doi.org/10.18687/LACCEI2023.1.1.1530
dc.relation/*ref*/Y. Feng, L. Yang, J. Liu, and B. E. Logan, “Electrochemical technologies for wastewater treatment and resource reclamation,” Environ. Sci. Water Res. Technol., vol. 2, no. 5, pp. 800-831, May. 2016. https://doi.org/10.1039/C5EW00289C
dc.relation/*ref*/J. Rumky, A. Deb, M. Joon Shim, E. Laakso, and E. Repo, “A review on the recent advances in electrochemical treatment technologies for sludge dewatering and alternative uses,” J. Hazardous Mater., vol. 11, p. 100341, Aug. 2023. https://doi.org/10.1016/j.hazadv.2023.100341
dc.relation/*ref*/A. Shahedi, A. K. Darban, F. Taghipour, and A. Jamshidi-Zanjani, “A review on industrial wastewater treatment via electrocoagulation processes,” Curr. Opin. Electrochem., vol. 22, pp. 154-169, Aug. 2020. https://doi.org/10.1016/j.coelec.2020.05.009
dc.relation/*ref*/C. Femina Carolin, P. Senthil Kumar, A. Saravanan, G. Janet Joshiba, and M. Naushad, “Efficient techniques for the removal of toxic heavy metals from aquatic environment: A review,” J. Environ. Chem. Engin., vol. 5, no. 3, pp. 2782-2799, Jun. 2017. https://doi.org/10.1016/j.jece.2017.05.029
dc.relation/*ref*/C. A. Martínez-Huitle, and E. Brillas, “Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods: A general review,” Appl. Catal. B: Environ., vol. 87, no. 3-4., pp. 105-145, Apr. 2009. https://doi.org/10.1016/j.apcatb.2008.09.017
dc.relation/*ref*/N. Yasri, J. Hu, M. G. Kibria, and E. P. L. Roberts, “Electrocoagulation Separation Processes,” in Multidisciplinary Advances in Efficient Separation Processes, I. Chernyshova, S. Ponnurangam, and Q. Liu, Eds., Washington, USA: American Chemical Society, 2020, pp. 167–203. https://pubs.acs.org/doi/abs/10.1021/bk-2020-1348.ch006
dc.relation/*ref*/D. Sharma, P. Kumar Chaudhari, S. Dubey, and A. Kumar Prajapati, “Electrocoagulation Treatment of Electroplating Wastewater: A Review,” J. Environ. Engin., vol. 146, no. 10, Jul. 2020. https://doi.org/10.1061/(ASCE)EE.1943-7870.0001790
dc.relation/*ref*/A. Adeyemi Oladipo, F. Suleiman Mustafa, O. Nestor Ezugwu, and M. Gazi, “Efficient removal of antibiotic in single and binary mixture of nickel by electrocoagulation process: Hydrogen generation and cost analysis,” Chemosphere, vol. 300, p. 134532, Aug. 2022. https://doi.org/10.1016/j.chemosphere.2022.134532
dc.relation/*ref*/L. Yang et al., “Electrochemical recovery and high value-added reutilization of heavy metal ions from wastewater: Recent advances and future trends,” Environ. Int., vol. 152, p. 106512, Jul. 2021. https://doi.org/10.1016/j.envint.2021.106512
dc.relation/*ref*/F. Fu, and Q. Wang, “Removal of heavy metal ions from wastewaters: A review,” J. Environ. Manage., vol. 92, no. 3, pp. 407-418, Mar. 2011. https://doi.org/10.1016/j.jenvman.2010.11.011
dc.relation/*ref*/Y. Zhu, W. Fan, T. Zhou, and X. Li, “Removal of chelated heavy metals from aqueous solution: A review of current methods and mechanisms,” Sci. Total Environ., vol. 678, pp. 253-266, Aug. 2019. https://doi.org/10.1016/j.scitotenv.2019.04.416
dc.relation/*ref*/W. Wang, and K. Sun, “Influence of current density on the microstructure of carbon-based cathode materials during aluminum electrolysis,” Appl. Sci. (Switz.), vol. 10, no. 7, p. 2228, Apr. 2020. https://doi.org/10.3390/app10072228
dc.relation/*ref*/O. V. Ogechi, and O. A. Ikejiofor, “A Review of the Essence of Stability Constants in the Thermodynamic Assessments of Chemical Compounds,” International Journal of Anesthesiology and Practice, vol. 1, no. 1, Dec. 2022. https://doi.org/10.58489/2994-2624/002
dc.relation/*ref*/J.-H. Chang, A. V. Ellis, C.-T. Yan, and C.-H. Tung, “The electrochemical phenomena and kinetics of EDTA-copper wastewater reclamation by electrodeposition and ultrasound,” Sep. Purif. Technol., vol. 68, no. 2, pp. 216–221, Aug. 2009. https://doi.org/10.1016/j.seppur.2009.05.014
dc.relation/*ref*/H. I. Maarof, W. M. A. Wan Daud, and M. Kheireddine Aroua, “Recent trends in removal and recovery of heavy metals from wastewater by electrochemical technologies,” Rev. Chem. Engin., vol. 33, no. 4, pp. 359–386, 2017. https://doi.org/10.1515/revce-2016-0021
dc.relation/*ref*/W. Guan, S. Tian, D. Cao, Y. Chen, and X. Zhao, “Electrooxidation of nickel-ammonia complexes and simultaneous electrodeposition recovery of nickel from practical nickel-electroplating rinse wastewater,” Electrochim. Acta, vol. 246, pp. 1230–1236, Aug. 2017. https://doi.org/10.1016/j.electacta.2017.06.121
dc.relation/*ref*/L. Wu, S. Garg, J. Xie, C. Zhang, Y. Wang, and T. David Waite, “Electrochemical Removal of Metal-Organic Complexes in Metal Plating Wastewater: A Comparative Study of Cu-EDTA and Ni-EDTA Removal Mechanisms,” Environ. Sci. Technol., vol. 57, no. 33, pp. 12476–12488, Aug. 2023. https://doi.org/10.1021/acs.est.3c02550
dc.relation/*ref*/M. del M. Cerrillo-Gonzalez, M. Villen-Guzman, J. M. Rodriguez-Maroto, and J. M. Paz-Garcia, “Metal Recovery from Wastewater Using Electrodialysis Separation,” Metals, vol. 14, no. 1, p. 38, Dec. 2024. https://doi.org/10.3390/met14010038
dc.relation/*ref*/N. Pismenskaya et al., “A review on ion-exchange membranes fouling during electrodialysis process in food industry, part 2: Influence on transport properties and electrochemical characteristics, cleaning and its consequences,” Membranes (Basel), vol. 11, no. 11, p. 811, Oct. 2021. https://doi.org/10.3390/membranes11110811
dc.relation/*ref*/H. Strathmann, “Electrodialysis, a mature technology with a multitude of new applications,” Desalination, vol. 264, no. 3, pp. 268–288, Dec. 2010. https://doi.org/10.1016/j.desal.2010.04.069
dc.relation/*ref*/L. Gurreri, A. Tamburini, A. Cipollina, and G. Micale, “Electrodialysis applications in wastewater treatment for environmental protection and resources recovery: A systematic review on progress and perspectives,” Membranes, vol. 10, no. 7, p. 146, Jul. 2020. https://doi.org/10.3390/membranes10070146
dc.relation/*ref*/C. Jiang et al., “Complexation Electrodialysis as a general method to simultaneously treat wastewaters with metal and organic matter,” Chem. Engin. J., vol. 348, pp. 952–959, Sep. 2018. https://doi.org/10.1016/j.cej.2018.05.022
dc.relation/*ref*/S. Oladejo Ganiyu, C. A. Martínez-Huitle, and M. A. Oturan, “Electrochemical advanced oxidation processes for wastewater treatment: Advances in formation and detection of reactive species and mechanisms,” Curr. Opin. Electrochem., vol. 27, p. 100678, Jun. 2021. https://doi.org/10.1016/j.coelec.2020.100678
dc.relation/*ref*/E. A. Serna-Galvis, K. E. Berrio-Perlaza, and R. A. Torres-Palma, “Electrochemical treatment of penicillin, cephalosporin, and fluoroquinolone antibiotics via active chlorine: evaluation of antimicrobial activity, toxicity, matrix, and their correlation with the degradation pathways,” Environ. Sci. Pollut. Res., vol. 24, no. 30, pp. 23771–23782, Oct. 2017. https://doi.org/10.1007/s11356-017-9985-2
dc.relation/*ref*/H. Ren et al., “Removal of ofloxacin from wastewater by chloride electrolyte electro-oxidation: Analysis of the role of active chlorine and operating costs,” Sci. Total Environ., vol. 850, p. 157963, Dec. 2022. https://doi.org/10.1016/j.scitotenv.2022.157963
dc.relation/*ref*/D. Zhi, J. Qin, H. Zhou, J. Wang, and S. Yang, “Removal of tetracycline by electrochemical oxidation using a Ti/SnO2–Sb anode: characterization, kinetics, and degradation pathway,” J. Appl. Electrochem., vol. 47, no. 12, pp. 1313–1322. Dec. 2017. https://doi.org/10.1007/s10800-017-1125-7
dc.relation/*ref*/M. Hosseini, H. Rasoulzadeh, H. Akbari, H. Akbari, and A. Adibzadeh, “Photo-electrocatalytic degradation of remdesivir from aqueous solutions using Ni-doped ZnO nanocomposite: Kinetic, degradation pathway, toxicity reduction and reusability,” J. Photochem. Photobiol. A. Chem., vol. 450, p. 115416, May 2024. https://doi.org/10.1016/j.jphotochem.2023.115416
dc.relation/*ref*/S. Ye, Y. Chen, X. Yao, and J. Zhang, “Simultaneous removal of organic pollutants and heavy metals in wastewater by photoelectrocatalysis: A review,” Chemosphere, vol. 273, p. 128503, Jun. 2021. https://doi.org/10.1016/j.chemosphere.2020.128503
dc.relation/*ref*/K. Changanaqui, E. Brillas, P. L. Cabot, H. Alarcón, and I. Sirés, “Complete abatement of the antibiotic ciprofloxacin from water using a visible-light-active nanostructured photoanode,” Chemosphere, vol. 352, p. 141396, Mar. 2024. https://doi.org/10.1016/j.chemosphere.2024.141396
dc.relation/*ref*/L. Liu, R. Li, Y. Liu, and J. Zhang, “Simultaneous degradation of ofloxacin and recovery of Cu(II) by photoelectrocatalysis with highly ordered TiO2 nanotubes,” J. Hazardous Mater., vol. 308, pp. 264–275, May. 2016. https://doi.org/10.1016/j.jhazmat.2016.01.046
dc.relation/*ref*/H. He et al., “Photoelectrocatalytic coupling system synergistically removal of antibiotics and antibiotic-resistant bacteria from aquatic environment,” J. Hazardous Mater., vol. 424, no. part C, p. 127553, Feb. 2022. https://doi.org/10.1016/j.jhazmat.2021.127553
dc.relation/*ref*/D. Wu, D. Lu, F. Sun, and Y. Zhou, “Process optimization for simultaneous antibiotic removal and precious metal recovery in an energy neutral process,” Sci. Total Environ., vol. 695, p. 133914, Dec. 2019. https://doi.org/10.1016/j.scitotenv.2019.133914
dc.relation/*ref*/L. Yang, Y. Hu, and L. Zhang, “Architecting Z-scheme Bi2S3@CoO with 3D chrysanthemums-like architecture for both photoeletro-oxidization and -reduction performance under visible light,” Chem. Engin. J., vol. 378, p. 122092, Dec. 2019. https://doi.org/10.1016/j.cej.2019.122092
dc.relation/*ref*/C. Sun, J. Wang, C. Gu, C. Wang, S. Sun, and P. Song, “MOF-derived N-Co/Fe-PC composite as heterogeneous electro-Fenton catalysis combined with electrocoagulation process for enhanced degradation of Cu-CIP complexes from wastewater,” Chem. Engin. J., vol. 452, no. Part 4, p. 139592, Jan. 2023. https://doi.org/10.1016/j.cej.2022.139592
dc.relation/*ref*/J. Qin, S. Ye, K. Yan, and J. Zhang, “Visible light-driven photoelectrocatalysis for simultaneous removal of oxytetracycline and Cu (II) based on plasmonic Bi/Bi2O3/TiO2 nanotubes,” J. Colloid Interface Sci., vol. 607, pp. 1936–1943, Feb. 2022. https://doi.org/10.1016/j.jcis.2021.10.008
dc.relation/*ref*/C. Volk, L. Wood, B. Johnson, J. Robinson, H. W. Zhu, and L. Kaplan, “Monitoring dissolved organic carbon in surface and drinking waters,” J. Environ. Monit., vol. 4, no. 1, pp. 43–47, Jan. 2002. https://doi.org/10.1039/B107768F
dc.relation/*ref*/X. Zhu, X. Li, Y. Shan, and X. Zhao, “Treatment of catalyst wastewater through an environmentally friendly electrodeposition-precipitation-electrooxidation coupling process: Recovery of copper and silicate, and removal of COD,” Sep. Purif. Technol., vol. 317, p. 123858, Jul. 2023. https://doi.org/10.1016/j.seppur.2023.123858
dc.relation/*ref*/T. Paul, P. L. Miller, and T. J. Strathmann, “Visible-light-mediated TiO2 photocatalysis of fluoroquinolone antibacterial agents,” Environ. Sci. Technol., vol. 41, no. 13, pp. 4720–4727, Jun. 2007. https://doi.org/10.1021/es070097q
dc.relation/*ref*/A. Kurnia Asih, R. Desni Yetti, and B. Chandra, “Photodegradation of Antibiotic Using TiO2 as a Catalyst: A Review,” Int. J. Pharm. Sci. Med., vol. 6, no. 2, pp. 37–43, Feb. 2021. https://ijpsm.com/Publish/Feb2021/V6I205.pdf
dc.relation/*ref*/B. A. Koiki, B. O. Orimolade, B. N. Zwane, D. Nkosi, N. Mabuba, and O. A. Arotiba, “Cu2O on anodised TiO2 nanotube arrays: A heterojunction photoanode for visible light assisted electrochemical degradation of pharmaceuticals in water,” Electrochim. Acta, vol. 340, p. 135944, Apr. 2020. https://doi.org/10.1016/j.electacta.2020.135944
dc.relation/*ref*/H. Zeng, S. Tian, H. Liu, B. Chai, and X. Zhao, “Photo-assisted electrolytic decomplexation of Cu-EDTA and Cu recovery enhanced by H2O2 and electro-generated active chlorine,” Chem. Engin. J., vol. 301, pp. 371–379, Oct. 2016. https://doi.org/10.1016/j.cej.2016.04.006
dc.relation/*ref*/K. H. Hama Aziz, and F. S. Mustafa, “Advanced oxidation processes for the decontamination of heavy metal complexes in aquatic systems: A review,” Case Studies Chem. Environ. Engin., vol. 9, p. 100567, Jun. 2024. https://doi.org/10.1016/j.cscee.2023.100567
dc.relation/*ref*/
dc.rightsDerechos de autor 2025 TecnoLógicases-ES
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/4.0es-ES
dc.sourceTecnoLógicas; Vol. 28 No. 63 (2025); e3344en-US
dc.sourceTecnoLógicas; Vol. 28 Núm. 63 (2025); e3344es-ES
dc.source2256-5337
dc.source0123-7799
dc.subjectcontaminantes emergenteses-ES
dc.subjectdegradación de medicamentoses-ES
dc.subjectfotoelectrocatálisises-ES
dc.subjectrecuperación de metaleses-ES
dc.subjectemerging pollutantsen-US
dc.subjectdrug degradationen-US
dc.subjectphotoelectrocatalysisen-US
dc.subjectmetal recoveryen-US
dc.titleRemoval of Antibiotic-Metal Complexes in Wastewater by Electrochemical Methods: A Reviewen-US
dc.titleEliminación de complejos antibiótico-metal en aguas residuales mediante métodos electroquímicos: una revisiónes-ES
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.typeReview Articleen-US
dc.typeArtículos de revisiónes-ES

Archivos

Bloque original

Mostrando 1 - 4 de 4
Miniatura
Nombre:
3344_MPU_VF_v3_1.pdf
Tamaño:
634.62 KB
Formato:
Adobe Portable Document Format
Descargar
Miniatura
Nombre:
3678.html
Tamaño:
102.57 KB
Formato:
Hypertext Markup Language
Descargar
Miniatura
Nombre:
344281872003.xml
Tamaño:
244 KB
Formato:
Extensible Markup Language
Descargar
Miniatura
Nombre:
344281872003.epub
Tamaño:
834.79 KB
Formato:
Electronic publishing
Descargar

Colecciones

Revista TecnoLógicas - Cosecha Portal de Revistas