Iron Oxides as Catalysts of Fenton-Type Processes with Potential Application in Pollutant Removal Technologies

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dc.creatorGarzón-Cucaita , Valentina
dc.creatorCarriazo, José G.
dc.date2022-11-22
dc.date.accessioned2025-10-01T23:52:50Z
dc.descriptionThe designing of new technologies for wastewater treatment is needed. These procedures should have greater efficiency and broad engineering application scope. Among these technologies, the advanced oxidation processes (AOP) have shown high efficiency and potential application in the degradation of hazardous pollutants. Fenton and Fenton-type reactions constitute the most widely used group of AOPs, due to their great oxidizing power and feasibility of application. The iron oxides are stable, non-toxic, and abundant; they have been extensively studied as catalysts for Fenton-type systems. The aim of this work is to show the state of the art on the application of iron oxides as catalysts in these systems. Methodologically, a systematic bibliographic review was carried out on the iron oxides used in Fenton-type processes, using the Scopus database with a search formula that included the appropriate descriptors and boolean operators. As a result, a wide variety of structures with different characteristics and catalytic performance were identified, classified, and analyzed. As conclusion, the most studied species like heterogeneous Fenton catalysts have been magnetite (Fe3O4), hematite (α-Fe2O3), goethite (α-FeOOH) and ferrihydrite (FeOOH). They show different levels of degradation of organic contaminants, depending on the type of substrate, pH, temperature, and concentration of H2O2. In addition, some modifications focused on improving the catalytic efficiency were described: the use of UV-Vis radiation, incorporation of metallic Fe (Fe0) or transition metals (Co, Cu and Mn), catalytic supports, and the control of particle morphology.en-US
dc.descriptionExiste la necesidad de diseñar nuevas tecnologías para el tratamiento de aguas residuales, con mayor eficiencia y alcance de aplicación ingenieril. Entre dichas tecnologías, los procesos avanzados de oxidación (AOP, por sus siglas en inglés) han demostrado alta eficiencia y potencial aplicación en la degradación de contaminantes peligrosos. Las reacciones Fenton y tipo Fenton constituyen el grupo de AOP de uso más extendido, debido a su gran poder oxidante y viabilidad de aplicación. Los óxidos de hierro, estables, no tóxicos y abundantes, han sido ampliamente estudiados como catalizadores de sistemas tipo Fenton. El objetivo del presente estudio fue mostrar el estado actual sobre los avances recientes en la aplicación de los óxidos de hierro como catalizadores en este tipo de sistemas. Metodológicamente, se realizó una revisión bibliográfica sistemática sobre óxidos de hierro empleados en procesos tipo Fenton, usando la base de datos Scopus con una fórmula de búsqueda que incluyó los descriptores y operadores booleanos apropiados. Como resultado, se identificó, clasificó y analizó una amplia variedad de estructuras con diferentes características y desempeño catalítico. En conclusión, las especies más estudiadas como catalizadores han sido magnetita (Fe3O4), hematita (α-Fe2O3), goethita (α-FeOOH) y ferrihidrita (FeOOH), mostrando diferentes niveles de degradación de contaminantes orgánicos, dependiendo del tipo de sustrato, pH, temperatura y concentración de H2O2. Además, se describieron algunas modificaciones enfocadas a mejorar su eficiencia catalítica: empleo de radiación UV-Vis, incorporación de Fe metálico (Fe0) o metales de transición (Co, Cu y Mn), soportes catalíticos y control de la morfología de partículas.es-ES
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dc.identifierhttps://revistas.itm.edu.co/index.php/tecnologicas/article/view/2393
dc.identifier10.22430/22565337.2393
dc.identifier.urihttps://hdl.handle.net/20.500.12622/7842
dc.languagespa
dc.publisherInstituto Tecnológico Metropolitano (ITM)es-ES
dc.relationhttps://revistas.itm.edu.co/index.php/tecnologicas/article/view/2393/2631
dc.relationhttps://revistas.itm.edu.co/index.php/tecnologicas/article/view/2393/2635
dc.relationhttps://revistas.itm.edu.co/index.php/tecnologicas/article/view/2393/2636
dc.relationhttps://revistas.itm.edu.co/index.php/tecnologicas/article/view/2393/2646
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dc.relation/*ref*/
dc.rightsDerechos de autor 2022 TecnoLógicases-ES
dc.rightshttp://creativecommons.org/licenses/by-nc-sa/4.0es-ES
dc.sourceTecnoLógicas; Vol. 25 No. 55 (2022); e2393en-US
dc.sourceTecnoLógicas; Vol. 25 Núm. 55 (2022); e2393es-ES
dc.source2256-5337
dc.source0123-7799
dc.subjectHeterogeneous catalysten-US
dc.subjectiron oxideen-US
dc.subjectadvanced oxidation processen-US
dc.subjectFenton reactionen-US
dc.subjectpollutant removal technologyen-US
dc.subjectCatalizador heterogéneoes-ES
dc.subjectóxido de hierroes-ES
dc.subjectproceso avanzado de oxidaciónes-ES
dc.subjectreacción Fentones-ES
dc.subjecttecnología de remoción de contaminantees-ES
dc.titleIron Oxides as Catalysts of Fenton-Type Processes with Potential Application in Pollutant Removal Technologiesen-US
dc.titleÓxidos de hierro como catalizadores de procesos tipo Fenton con potencial aplicación en tecnologías de remoción de contaminanteses-ES
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.typeReview Articleen-US
dc.typeArtículos de revisiónes-ES

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